Nesosilicates

The most abundant rock-forming minerals in the crust of the earth are the silicates. They are formed primarily of silicon and oxygen , together with various metals . The fundamental unit of these minerals is the silicon-oxygen tetrahedron. These tetrahedra have a pyramidal shape, with a relatively small, positively charged silicon cation (Si⁺⁴) in the center and four larger, negatively charged oxygen anions (O⁻²) at the corners, producing a net charge of −4. Aluminum cations (Al⁺³) may substitute for silicon, and various anions such as hydroxyl (OH⁻) or fluorine (F⁻) may substitute for oxygen. In order to form stable minerals, the charges that exist between tetrahedra must be neutralized. This can be accomplished by the sharing of oxygen cations between tetrahedra, or by the binding together adjacent tetrahedra with various metal cations. This in turn creates characteristic silicate structures that can be used to classify silicate minerals into cyclosilicates, inosilicates , nesosilicates, phyllosilicates, sorosilicates , and tectosilicates .

The simplest silicates are the nesosilicates, formed by individual silicon-oxygen tetrahedra. There is some substitution of aluminum for silicon in the tetrahedra, but not as much as in other types of silicate minerals. The negatively charged, isolated tetrahedra in nesosilicates are held together by various metal cations. The garnet group of nesosilicates is commonly found in metamorphic rocks and more rarely in igneous rocks , and the metal cations that are typically found in garnet minerals include aluminum, calcium, chromium, magnesium, manganese, and iron . Garnet minerals include almandine (Fe₃Al₂Si₃O₁₂), grossularite (Ca₃Al₂Si₃O₁₂), and uvarovite (Ca₃Cr₂Si₃O₁₂). The minerals of the olivine group are nesosilicates commonly found in iron- and magnesium-rich igneous rocks. The chemical formula of olivine is given as (Mg, Fe)₂SiO₄, but a complete solid solution exists between the end-members forsterite (Mg₂SiO₄) and fayalite (Fe₂SiO₄). The nesosilicate mineral zircon (ZrSiO₄) commonly forms in igneous rocks, and is so chemically stable that it becomes a common accessory mineral in many sediments and sedimentary rocks .

See also Mineralogy

nesosilicates (orthosilicates) A group of silicate minerals characterized by independent SiO₄ tetrahedra with no shared oxygens. The structure is held together by bonding with interstitial cations. The group includes olivine, garnet, sphene, zircon, staurolite, chloritoid, topaz, chondrodite, and the Al₂SiO₅ polymorphs.